Effect of Solvent Swelling on the reactivity of demineralized Turkish Lignite
نویسنده
چکیده
In this research, effect of demineralization and solvent swelling on pyrolysis kinetics was investigated. The experiments were carried out to investigate theeffects of solvent swelling with different solvents, such as THF, Pyridine and DMSO after demineralization with HCl, HNO3 and HF successively. To calculate the activation energies of lignite sample during pyrolysis, TGA analyses were performed with raw and swollen samples at 5, 10 and 20° C/min heating rates. Coast-Redfernmodel was used for the determination of kinetic parameters. According to the results, the macromolecular structure of lignite was affected from these hydrogen bonding solvents. So, the activation energies of swollen samples found to be less than the raw lignite sample for all heating rates. The reactivity of lignite samples can be ordered as follows; DMSO swollen sample > Pyridine swollen sample> THF swollen sample. Activation energy of DMSO swollen lignite sample is 10.62 kJ/mole whereas activation energies of pyridine swollen and THF swollen sample are 17.83, 25.76 kJ/mol, respectively at a heating rate of 10° C/min. The results indicated that, solvent swelling has catalytic effect on pyrolysis kinetics.
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